The OP’s car was pressure tested, and held the pressure which would have identified a leak in those components quite easily (less the expansion cap, which is where the pressure rig fits). I swapped my expansion cap after the same diagnosis, but it made no difference.
There is an overflow in the expansion reservoir; if the system pressure increases, either due to an airlock some where in the coolant system or exhaust gases over pressuring the coolant system, it ditches excess coolant out of the bottom centre of the tank - if the car is moving, there is obviously turbulent airflow around the engine bay which causes it to spay all over the place, which is what it looks like has happened in this instance.
When my water pump catastrophically failed it, dumped the entirety of the coolant, steam came out of the engine bay, but most of the coolant was on the sound proofing/oil pan cowling underneath the car.
I was replacing my Octavia regardless of this fault, but the heater matrix lost performance on the driver’s side only a few days before it was traded in, so had the entire system flushed and bled, which resolved the
problem before it was traded in - all of the bills and paperwork for the numerous coolant related checks were presented with the service history when I handed it over.
My opinion was that the heater matrix (on my car) was the most likely cause, and I would have DIY replaced it for peace of mind if I had retained the car; since trading in the car, there has been a significant increase in the number of cars suffering with heater matrix issues and the matrix is c.£100 for the part.
@YKFR Was the journey different from from those previously where you hadn’t experienced coolant loss?
For example - short journeys (30 mins) vs a long journey(2 hrs)? was the outside temperature cooler, resulting in the climate control heating the cabin as opposed to cooling it? Was the engine load higher on this particular journey - extra passengers/weight/towing or higher engine revs?