Super unleaded has a higher octane rating, which gives a much better burn in the chamber under compression. Tesco's has reputably shown the best results with the 99RON.
Some super unleaded fuels claim to have additives that are supposed to reduce carbonation of valves etc...
You may find that although S U/L is more expensive you could get more miles from a tank. It won't be enough to offset the cost of the fuel over U/L.
I find the newer 2.0T engines are more responsive to 98RON than the 1.8T's. Whilst my 1.8T idles better, and when running stage 2 I was able to tune the car more aggressively on the higher octane fuel, I'd say the difference was marginal. If you can afford it without having to sacrifice anything then do it as it will keep your engine in better condition, but even after adaptation don't expect night and day difference. Choose one and stick with it so the car doesn't have to keep adapting to new fuels.