I'd suggest that you buy new O-rings for any "quick release" hose you remove, the retaining spring should still be okay though, these hose ends might not be as easy as you would think to get back on and locked in place - well that was the case for me on my 2011 Audi S4, after refitting these hoses really do pull them well enough to dislodge any that are not fully locked in place.
Ideally all these newer engines need the coolant system to be vac'd down by coolant refill vacuum kit, then that kit is used to reflood the system, I've just done that job on my 2011 S4, it all went very well except for getting the "quick release/quick fit" to lock correctly first or even 10th time, very annoying!
You really should spend some time reading through that workshop manual document as it will advise you exactly
how to achieve this with minimum possibility of ending up damaging your engine due to localised overheating, coolant changing, it seems has become a bit more of a "fine art" than what it used to be.
Personally, I'd just try to rinse out the base of the radiator as that is where any iron fall out will have landed and stayed out of suspension in the coolant.
VW Group parts departments sell the genuine latest G12evo in one litre containers premixed to 50% for £7.13 inc VAT a container - well that price was from a month ago, the previous coolant, G13 should now not be available from VW Group outlets, which is a good thing - I think.
I can't advise you on the capacity of that system, but if I was you, I'd be doing what I did and that was to collect all the coolant you drain out and measure it, I'm suggesting that you do that for two reasons, firstly you will know how much new coolant to buy, and secondly, you will know when you have managed to get enough coolant back into the system so that you can safely run the engine to let it purge out the remaining air still lodged in the system.