Erm, what do you think is happening inside your engine?
It's simple chemistry - the spark causes the petrol/air mixture to explode, the force of which drives the pistons. 99 RON fuel produces more explosive force per unit volume of petrol. Therefore, you require less volume of 99 RON fuel to provide the same driving force to the pistons compared to 95 RON.
LC, LCR both adapt the fuel/air mixture depending on the grade of fuel and intake volume of air + some other parameters. When cruising at a constant speed, your car will consume less 99RON fuel than 95, resulting in improved MPG.
But it doesn't produce more explosive force. That's not the point of higher octane fuel. Hence my last comment.